[PDF] Chemistry gains a new element: Z=106 | Semantic Scholar (2024)

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@article{Gggeler1998ChemistryGA, title={Chemistry gains a new element: Z=106}, author={Heinz Walter G{\"a}ggeler}, journal={Journal of Alloys and Compounds}, year={1998}, volume={271}, pages={277-282}, url={https://api.semanticscholar.org/CorpusID:96419596}}
  • H. Gäggeler
  • Published 12 June 1998
  • Chemistry
  • Journal of Alloys and Compounds

8 Citations

Background Citations

1

8 Citations

Chemistry of superheavy elements.
    M. Schädel

    Chemistry

    Angewandte Chemie

  • 2006

These results place the architecture of the far-end of the Periodic Table on the test bench and probe the increasingly strong relativistic effects that influence the chemical properties there.

Chemistry of superheavy elements
    M. Schädel

    Chemistry

    Philosophical Transactions of the Royal Society A…

  • 2015

A test bench is established to challenge the validity and predictive power of modern fully relativistic quantum chemical models and to probe ‘relativistically’ influenced chemical properties and the architecture of the periodic table at its farthest reach.

  • 104
  • PDF
Development of nuclear chemistry at Mainz and Darmstadt
    J. Kratz

    Chemistry, Physics

    Radiochimica Acta

  • 2018

Abstract This review describes some key accomplishments of Günter Herrmann such as the establishment of the TRIGA Mark II research reactor at Mainz University, the identification of a large number of

  • 4
  • PDF
20 Chemistry of Transactinides
    J. Kratz

    Chemistry

  • 2011

In this chapter, the chemical properties of the man-made transactinide elements rutherfordium, Rf (element 104), dubnium, Db (element 105), seaborgium, Sg (element 106), bohrium, Bh (element 107),

  • 18
Gas Chromatographic Studies of Oxide and Hydroxide Species of Tungsten - Model Experiments with Respect to the Physico-Chemical Characterization of Seaborgium (Element 106)
    A. VahleS. Hübener E. Jäger

    Chemistry, Materials Science

  • 1999

The adsorption/desorption behavior of carrier-free W on quartzglass surfaces in dry and moist oxygen was studied by off-line thermochromatography in the temperature ränge 330—1480 K. In dry oxygen W

  • 15
  • PDF
Gas phase chemistry of technetium and rhenium oxychlorides
    R. EichlerB. EichlerH. GäggelerD. JostD. PiguetA. Türler

    Chemistry

  • 2000

The chloride and oxychloride chemistry of the group 7 elements Tc and Re was investigated in order to develop an experimental approach to a gas chemical characterisation of bohrium (Bh, element 107).

  • 18
Extraction behavior of short-lived isotopes of Mo/W using α-benzoinoxime: A model system for the study of seaborgium
    F. FanF. Lei Z. Qin

    Chemistry, Materials Science

  • 2009

Abstract The liquid-liquid extraction behavior of short-lived molybdenum and tungsten isotopes from HCl and HNO3 as well as HF/HNO3 acid media was studied using the α-benzoinoxime/chloroform system.

  • 6
Radioelements

    Nuclear and Radiochemistry

  • 2021
  • 1

18 References

Chemical properties of element 106 (seaborgium)
    M. SchädelW. Brüchle A. Yakuschev

    Chemistry

    Nature

  • 1997

The synthesis, via nuclear fusion reactions, of elements heavier than the actinides, allows one to probe the limits of the periodic table as a means of classifying the elements. In particular,

  • 122
  • PDF
First Aqueous Chemistry with Seaborgium (Element 106)
    M. SchädelW. Brüchle Y. Oura

    Chemistry

  • 1997

Chemical separations of element 106 (seaborgium, Sg) were performed in aqueous solutions. The isotopes 265 Sg and 266 Sg, produced in the 248 Cm+ 22 Ne reaction, were continuously transported to the

  • 63
  • PDF
Chemical Properties of Element 105 in Aqueous Solution: Cation Exchange Separations with α-Hydroxyisobutyric Acid
    M. SchädelW. Brächte D. Hoffman

    Chemistry

  • 1992

Studies of the complexation of element 105 by unbuffered ahydroxyisobutyric acid (a-HiB) and its elution from strongly acidic cation exchange resin were performed on a mixture of 34-s ^ " H a and

  • 37
Chemical Properties of Element 105 in Aqueous Solution: Halide Complex Formation and Anion Exchange into Triisoctyl Amine
    J. KratzH. Zimmermann C. Lienert

    Chemistry

  • 1989

Studies of the halide complexation of element 105 in aqueous solution were performed on 34-s 2 6 2 Ha produced in the 2 4 Bk( l O,5n) reaction. The 2 6 2 Ha was detected by measuring the fission and

  • 65
  • PDF
Ionization potentials and radii of atoms and ions of element 104 (unnilquadium) and of hafnium (2 +) derived from multiconfiguration Dirac-Fock calculations
    Elijah JohnsonB. FrickeO. KellerC. W. NestorT. C. Tucker

    Chemistry, Physics

  • 1990

Multiconfiguration relativistic Dirac–Fock (MCDF) values have been computed for the first four ionization potentials (IPs) of element 104 (unnilquadium) and of the other group 4 elements (Ti, Zr, and

  • 52
  • PDF
Group 6 Dioxydichlorides MO2Cl2 (M = Cr, Mo, W, and Element 106, Sg): The Electronic Structure and Thermochemical Stability
    V. P. andB. Fricke

    Chemistry

  • 1996

Results of the Dirac−Slater discrete-variational calculations are presented for the group 6 dioxydichlorides, MO2Cl2 (M = Cr, Mo, W, and element 106, Sg). Estimates of the bond strengths and

  • 31
On-line Gas Chromatographie Studies of Chlorides of Rutherfordium and hom*ologs Zr and Hf
    B. KadkhodayanA. Türler D. Hoffman

    Chemistry

  • 1996

Gas-phase isothermal chromatography is a method by which volatile compounds of different chemical elements can be separated. The technique, coupled with theoretical modeling of the processes

  • 58
  • PDF
Chemical Properties of Element 105 in Aqueous Solution: Back Extraction from Triisooctyl Amine into 0.5 M HCl
    H. ZimmermannM. Gober A. Weber

    Chemistry

  • 1993

Previous studies of the halide complex formation of element 105 and its anion exchange with triisooctyl amine (TIOA) were continued. The experiments were performed on a one-minute time scale with the

  • 36
  • PDF
First confirmation of the discovery of element 106.
    GregorichLane Hoffman

    Physics

    Physical review letters

  • 1994

The 0.9-s [sup 263]106 was produced at the Lawrence Berkeley Laboratory 88-Inch Cyclotron via the [sup 249]Cf([sup 18]O,4[ital n])[sup 263)106 reaction using a beam of 95-MeV [sup 18)O ions.

  • 26
  • PDF
On-line Gas Phase Chromatography with Chlorides of Niobium and Hahnium (Element 105)
    Α. TürlerΒ. Eichler S. Hübener

    Chemistry, Physics

  • 1996

The retention behavior of volatile chlorides and oxychlorides of short-lived isotopes of group 5 elements Nb and 105 (Ha = hahnium) in quartz columns was studied using on-line isothermal gas

  • 36
  • PDF

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